The lyrics that gets me hard is And you can do this, oh baby, if you try.
Just--honestly, I'm gonna go with my original response. OH my god.
I don't think I'll ever top my love for the "Simple Man" montage from 5x03 (well, maybe 6x01 and "Beautiful Loser"--those might be tied), but SPN is more than welcome to continue to try. We've had some wonderful ones since! I love Castiel's Yardbirds return post-Emmanuel. The Warren Zevon at the end of 11x11. The Rolling Stones at the end of 12x13. SIMPLE MAN, THOUGH. Edit: God Was Never On Your Side at the end of 14x20!